The OVA Astaroette no Omocha is a three part short story series. In the first story, Lotte and Asuha find themselves searching for details about their school project. In the second bit, is the backstory to how Zelda came to be Lotte's bodyguard. The final of the three, is a flashback of how the queen met Naoya and how they conceived Asuha ten years prior to the events in the anime. (Source: ANN)

The film's story begins when Arata inadvertently touches "Hermes Apocrypha," Lilith's Grimoire. Suddenly, he is enveloped by a bright white light, and a girl appears before him. She calls herself Lilim, and treats both Arata and Lilith as her parents. At the same time she appears, something changes in the world. The forbidden Eternal Library awakens. In the Library is sealed the ultimate culmination of Alchemy, the White Demon Lord. The White Demon Lord plots to eliminate Arata and the Trinity Seven to usurp the position of Demon Lord. Bristling with untold power, the White Demon Lord attacks Arata, and triggers a desperate crisis where Arata and the Trinity Seven must save the world in this last battle. (Source: ANN)

Heavens Library to Crimson Lord brings back Arata, Lilith, and the rest of the Trinity Seven to face off against the greatest enemy in the history of the Trinity Seven; Lilith's own father, who is revealed to be the strongest Demon Lord, challenges Arata who is now a Demon Lord candidate. (Source: Avex Pictures, edited)

A special included on the 7th DVD release, commonly known as "Episode 14". It features nudity and adult situations which were not present in the original series.