A mysterious force binds Ash to the Mythical Pokemon Volcanion when it falls from the sky. Volcanion can't get away, and Ash is dragged along as it continues on its mission. They arrive in a city of cogs and gears, where a corrupt minister has stolen the ultimate invention: the Artificial Pokemon Magearna, created 500 years ago. The minister plans to use Magearna's mysterious power to take control of the mechanical kingdom.

(Source: ANN)

Hayato Izumi is running for student council president. He's studious, responsible, down to earth...and completely outmatched by his rival, Ui Wakana. Ui wins in a landslide after promising comprehensive sex education, free condoms, and other exciting reforms. Bloodied but not discouraged, Hayato licks his wounds and settles for vice president. Then Ui moves in with him. As it turns out, their parents made a drunken promise decades ago that their children would one day marry. Ui and Hayato must now balance school life with matrimony, keeping their relationship secret from a prudish student body and learning to live with each other. Can they keep the student council in line and find happiness together? Find out in Okusama ga Seitokaichou!

A heartwarming story about a stray black cat, who was given blood from a vampire. He was taken in by a girl called Misaki and started to live with her. Nyanpire's favorite phrase is "Give me blood nya."

The final DVD volume contains two specials: Tokimeki no Yuuki Episode 18 (sometimes labeled 17.5), which was never broadcast on TV. It features the swim captain, Utsumi Koayu. Tokimeki no Sentaku Episode 25.5, a recap of all episodes but the last, which was initially displayed at the Konami booth for the Tokyo International Anime Fair in 2007.