Saito Hiraga and Louise Françoise Le Blanc de La Vallière go on the offensive after the events of Zero no Tsukaima: Princesses no Rondo. Together, they face off against King Joseph in the Holy City of Romalia with the help of two others who control the power of the “void”. But in the midst of the many conflicts ahead of them, an ancient evil begins to stir in the shadows. Will their close bonds blossom into something more or will they be shattered through the ever increasing difficulty of the tasks that they must undertake? Zero no Tsukaima F follows the story of Louise and Saito as they face their final challenges together.

Specials included in the anime's BD/DVD releases. The first disc release features "Heya Camp Episode 0," a story before Nadeshiko joins the club.

Akutabe is a detective who summons devils to solve the troubles of his clients. One day, a low class devil Azazel Atsushi is summoned by Akutabe and is used harshly by him and his assistant Rinko.

Continuing their treks through the high peaks of Japan, the mountaineering girls are back for more! First-year high school student Aoi Yukimura, a shy girl with a fear of heights, and her wildly energetic friend Hinata Kuraue set out once again to conquer the perils of backyard camping trips, summer homework, and even a climb on the mountain of their dreams. Joined by middle school student Kokona Aoba and their knowledgeable upperclassman Kaede Saitou, the squad members are ready to take on whatever slopes and challenges they might face, no matter how steep. Through their shared hobby of mountain climbing, they bond closer than ever and even make new friends on trails all over the country. Whether it is just a local hill or the tallest mountain around, nothing is too much for Aoi and the crew to handle. They will climb, stumble, and rise to even greater heights together! [Written by MAL Rewrite]